Extraction of barium by a nitrobenzene solution of bis-1,2-dicarbollylcobaltate in the presence of 15-crown-5

被引：0

作者：

P. Vaňura

E. Makrlík

机构：

[1] Prague Institute of Chemical Technology,Department of Analytical Chemistry

[2] Charles University,Faculty of Education

来源：

Journal of Radioanalytical and Nuclear Chemistry | 1998年 / 237卷

关键词：

Physical Chemistry; Inorganic Chemistry; Barium; 15C5; Stability Constant;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Extraction of barium by a nitrobenzene solution of bis-1,2-dicarbollylcobaltate in the presence of 15-crown-5 (15C5, L) has been investigated. The equilibrium data and the typical maxima concerning the dependencies of the Ba distribution ratios on the analytical concentration of 15C5 in the system under study can be explained assuming that the particles HL+, HL2+ and BaL22+ are extracted into the nitrobenzene phase. The values of the corresponding extraction and stability constants of the extracted species in nitrobenzene saturated with water have been determined.

引用

页码：11 / 14

页数：3

共 37 条

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