Molar and Partial Molar Excess Volumes of Benzene in Methyl Ester Solutions at 25°C

被引:0
作者
Alberto G. Camacho
Miguel A. Postigo
机构
[1] Universidad Nacional del Comahue,C´tedra de Fisicoquímica, Departamento de Química, Facultad de Ingeniería
来源
Journal of Solution Chemistry | 1998年 / 27卷
关键词
Excess molar volumes; methyl ester; benzene; Flory model; Priggogine–Flory–Patterson model;
D O I
暂无
中图分类号
学科分类号
摘要
Molar and partial molar excess volumes of mixtures of benzene with several methyl esters (from methanoate to decanoate) were determined, over the whole concentration range, at 25°C and atmospheric pressure from experimental densities and correlated by a suitable equation. The applicability of the Flory and Priggogine–Flory–Pattersort models for predicting molar excess volumes is tested. The calculated values with Flory and Priggogine–Flory–Patterson are similar and agree poorly with the experimental data.
引用
收藏
页码:719 / 729
页数:10
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