Nucleophilic substitution reactions of 2,4,6-tris(trinitromethyl)-1,3,5-triazine. 3. Reaction of 2,4,6-tris(trinitromethyl)-1,3,5-triazine with azides and hydrazine

被引：0

作者：

A. V. Shastin

T. I. Godovikova

B. L. Korsunskii

机构：

[1] Inst. of Prob. of Chemical Physics, Russian Academy of Sciences, Moscow Region

[2] N. D. Zelinsky Inst. of Organ. Chem.

来源：

Chemistry of Heterocyclic Compounds | 2003年 / 39卷 / 3期

关键词：

2,4,6-tris(trinitromethyl)-1,3,5-triazine; Hydrazine; Nucleophilic substitution; Sodium azide; Trimethylsilyl azide;

D O I：

10.1023/A:1023970928207

中图分类号：

学科分类号：

摘要：

As a result of nucleophilic substitution of the trinitromethyl groups in 2,4,6-tris(trinitromethyl)-1,3,5-triazine, the corresponding monoazido and diazido derivatives have been synthesized. The reaction of the starting triazine with hydrazine acetate in the presence of trifluoroacetic acid leads to 1-acetyl-2,2-bis[4,6-bis(trinitromethyl)-1,3,5-triazin-2-yl]hydrazine.

引用

页码：354 / 356

页数：2

共 5 条

[1]

Shastin A.V., Godovikova T.I., Korsunskii B.L., Khim. Geterotsikl. Soedin., (1998)

[2]

Shastin A.V., Godovikova T.I., Golova S.P., Kuz'min V.S., Khmel'nitskii L.I., Korsunskii B.L., Mendeleev Commun., (1995)

[3]

Shastin A.V., Godovikova T.I., Golova S.P., Khmel'nitskii L.I., Korsunskii B.L., Khim. Geterotsikl. Soedin., (1995)

[4]

Shastin A.V., Godovikova T.I., Golova S.P., Povorin M.V., Dmitriev D.E., Dekaprilevich M.O., Strelenko Yu.A., Struchkov Yu.T., Khmel'nitskii L.I., Korsunskii B.L., Khim. Geterotsikl. Soedin., (1995)

[5]

Smolin E.M., Rapoport L., s-Triazines and Derivatives, (1959)

← 1 →