N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties

被引:0
|
作者
A. D. Kharlamova
A. S. Abel
A. D. Averin
I. P. Beletskaya
机构
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
[2] A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences,undefined
来源
Russian Chemical Bulletin | 2019年 / 68卷
关键词
pyridines; quinolines; nitrogen-containing ligands; complexing; fluorescence;
D O I
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中图分类号
学科分类号
摘要
N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the CoII, NiII, QuII, ZnII and PbII cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.
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页码:597 / 600
页数:3
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