1,2 → 1,1-Migration of Silyl Group. Formation of 1,1-Bis(dichloromethylsilyl)-2-chloroethane in Catalytic Hydrochlorination of 1,2-Bis(dichloromethylsilyl)ethylene

被引：0

作者：

V. G. Lakhtin

V. D. Sheludyakov

V. M. Nosova

A. V. Kisin

E. A. Chernyshev

机构：

[1] Gosudarstvennyi nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii State Reseach Center of the Russian Federation,

来源：

Russian Journal of General Chemistry | 2001年 / 71卷

关键词：

Spectroscopy; Ethylene; Ethyl; FeCl3; General Formula;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Hydrochlorination of 1,2-bis(silyl)ethylenes of the general formula MenCl3-nSiCH = CHSiMen· Cl3-n, where n = 0-3, in the presence of FeCl3 was carried out. By NMR spectroscopy it was shown that in the case of the MeCl2Si derivative the major product is 1,1-bis(silyl)chloroethane and the minor product is its isomeric 1,2-bis(silyl)chloroethane (4:1). A reaction scheme is proposed, that includes isomerization of the intermediate bis(silyl)ethyl cation.

引用

页码：1554 / 1556

页数：2

共 10 条

[1] Lakhtin V.G.(1987)undefined Zh. Obshch. Khim. 57 1280-1286
[2] Sheludyakov V.D.(1985)undefined Zh. Obshch. Khim. 55 1345-1350
[3] Timofeev V.S.(1970)undefined Organomet. Chem. Rev., Part A 6 153-207
[4] Bochkarev V.N.(undefined)undefined undefined undefined undefined-undefined
[5] Slyusarenko T.F.(undefined)undefined undefined undefined undefined-undefined
[6] Nosova V.M.(undefined)undefined undefined undefined undefined-undefined
[7] Sheludyakov B.V.(undefined)undefined undefined undefined undefined-undefined
[8] Zhun' V.I.(undefined)undefined undefined undefined undefined-undefined
[9] Loginov S.V.(undefined)undefined undefined undefined undefined-undefined
[10] Jarvie A.W.P.(undefined)undefined undefined undefined undefined-undefined

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