Reactions of 9-Aroyl-3,3,6,6-Tetramethyl-1,2,3,4,5,6,7,8-Octahydroxanthene-1,8-Diones With Hydrazine and Methylhydrazine*

被引:0
作者
E. Bisenieks
J. Uldrikis
J. Poikans
L. Baumane
M. Petrova
E. Liepinsh
G. Duburs
机构
[1] Latvian Institute of Organic Synthesis,
来源
Chemistry of Heterocyclic Compounds | 2014年 / 49卷
关键词
9-aroyl-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroxanthene-1,8-dione; 3-aryl-5-hydrazono-7,7-dimethyl-5,6,7,8-tetrahydrocinnoline; 4,4'-bis(3-aryl-1,7,7-trimethyl-1,4,5,6,7,8-hexahydrocinnoline-5-ones); hydrazine; methylhydrazine;
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摘要
Reactions of 9-aroyl-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroxanthene-1,8-diones with hydrazine and methylhydrazine produced cinnoline derivatives. A homolytic cleavage of C–C bond in the intermediate product occured in the case of methylhydrazine, leading to the dimeric 4,4'-bis(3-aryl-1,7,7-trimethyl-1,4,5,6,7,8-hexahydrocinnoline-5-ones).
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页码:1653 / 1657
页数:4
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