Complex of triphenylantimony(v) catecholate with 5-(2,6-dimethylphenyl)-3-(4-pyridyl)-1-phenylformazan

被引：0
|
作者：
N. A. Protasenko
A. I. Poddel’skii
I. V. Smolyaninov
N. T. Berberova
G. K. Fukin
V. K. Cherkasov
G. A. Abakumov
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
[2] N. I. Lobachevsky Nizhny Novgorod State University,Research Group of Toxicology, Southern Scientific Center
[3] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2014年 / 63卷
关键词：
formazan ligand; organometallic derivatives of antimony(V); X-ray diffraction; cyclic voltammetry;
D O I：
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学科分类号：
摘要：
The complex of triphenylantimony(V) 3,6-di-tert-butylcatecholate with 5-(2,6-dimethylphenyl)-3-(4-pyridyl)-1-phenylformazan was synthesized and characterized by spectroscopic and electrochemical methods and by X-ray diffraction. In the crystal structure, there are intermolecular hydrogen bonds between the formazan ligands of adjacent molecules. The electrochemical transformations of the complex were investigated by cyclic voltammetry. It was shown that both the formazan and catecholate moieties are involved in redox processes.
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页码：930 / 937
页数：7
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