Low-temperature densification sintering and properties of CaAl2Si2O8 ceramics with MeO·2B2O3 (Me = Ca, Sr, Ba)

被引：0
作者：
Song Chen
De-gui Zhu
机构：
[1] Southwest Jiaotong University,School of Materials Science and Engineering
来源：
International Journal of Minerals, Metallurgy, and Materials | 2015年 / 22卷
关键词：
ceramics; densification; sintering; materials properties; anorthite; borates; alumina; quartz;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Dense CaAl2Si2O8 ceramics were prepared via a two-step sintering process at temperatures below 1000°C. First, pre-sintered CaAl2Si2O8 powders containing small amounts of other crystal phases were obtained by sintering a mixture of calcium hydroxide and kaolin powders at 950°C for 6 h. Subsequently, the combination of the pre-sintered ceramic powders with MeO·2B2O3 (Me = Ca, Sr, Ba) flux agents enabled the low-temperature densification sintering of the CaAl2Si2O8 ceramics at 950°C. The sintering behavior and phase formation of the CaAl2Si2O8 ceramics were investigated in terms of the addition of the three MeO·2B2O3 flux agents. Furthermore, alumina and quartz were introduced into the three flux agents to investigate the sintering behaviors, phase evolvements, microstructures, and physical properties of the resulting CaAl2Si2O8 ceramics. The results showed that, because of their low-melting characteristics, the MeO·2B2O3 (Me = Ca, Sr, Ba) flux agents facilitated the formation of the CaAl2Si2O8 ceramics with a dense microstructure via liquid-phase sintering. The addition of alumina and quartz to the flux agents also strongly affected the microstructures, phase formation, and physical properties of the CaAl2Si2O8 ceramics.
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页码：977 / 986
页数：9
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