Synthesis of N'-[4'-Benzo(15-Crown-5)]-4-Tolylaminoglyoxime and N'-[4'-Benzo(15-Crown-5)]-4-Chlorophenylaminoglyoxime and Their Complexes with Copper (II), Nickel (II) and Cobalt (II)

被引：0
作者：
Emin Karapinar
Emine Özcan
机构：
[1] Pamukkale University,Department of Chemistry, Faculty of Arts and Sciences
[2] Selçuk University,Department of Chemistry, Faculty of Arts and Sciences
来源：
Journal of inclusion phenomena and macrocyclic chemistry | 2003年 / 47卷
关键词：
crown ether; glyoximes; oximes; transition metal complexes;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
N'-[4'-benzo(15-crown-5)]-4-tolylaminoglyoxime (H2L1),the sodium chloride salt of H2L1 (H2L1...NaCl),N'-[4'-benzo(15-crown-5)]-4-chlorophenylaminoglyoxime(H2L2) and the sodium chloride salt of H2L2 (H2L2...NaCl)have been prepared from p-chlorophenylchloroglyoxime,p-tolylchloroglyoxime, 4'-aminobenzo[15-crown-5] and sodiumbicarbonate or sodium bicarbonate and sodium chloride. Nickel (II),cobalt (II) and copper (II) complexes of H2L and H2L...NaClhave a metal-ligand ratio of 1 : 2 and the ligand coordinatesthrough the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with1H NMR spectra of the ligands.
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页码：59 / 63
页数：4
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