Metastable Iron Sulfides

被引：0

作者：

V. V. Onufrienok

机构：

[1] Siberian State Transport University (Krasnoyarsk Branch),

来源：

Inorganic Materials | 2005年 / 41卷

关键词：

Sulfide; Hexagonal; Special Reference; Curie Temperature; Diffraction Study;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Data on various iron sulfides are analyzed with special reference to the presence of a ferrimagnetic phase with a Curie temperature of 580°C in pyrrhotine. X-ray diffraction studies and magnetic measurements provide substantial evidence for the existence of a metastable phase Fe2S3 with a hexagonal structure, embedded in the structure of pyrrhotine. The exchange integrals and temperature-dependent relative magnetization of iron sulfides are calculated in the molecular-field approximation for two-sublattice ferrimagnets. The calculation results agree well with experimental data.

引用

页码：650 / 653

页数：3

共 17 条

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