Synthesis of Electron-Donating Polymer Having Vinylogous TTF in the Main Chain

被引：0
|
作者：
Shinsuke Inagi
Kensuke Naka
Daisuke Iida
Yoshiki Chujo
机构：
[1] Graduate School of Engineering,Department of Polymer Chemistry
[2] Kyoto University,undefined
来源：
Polymer Journal | 2006年 / 38卷
关键词：
Tetrathiafulvalene; Electron-Donating Polymer; Oxidative Polymerization; Redox Polymer; Charge Transfer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The electron-donating polymer containing vinylogous TTF unit in the main chain was successfully obtained by oxidative polymerization of bisdithiafulvene (bisDTF) (1). The polymer was soluble in common organic solvents such as chloroform and toluene. Structural characterization of the polymer was provided by 1H and 13C NMR spectroscopies. The number-average molecular weight of the polymer was estimated as 5,400 by gel permeation chromatographic analysis (chloroform, polystyrene standards). Optical and electrochemical properties of the polymer were studied by UV-vis analysis and cyclic voltammetry. Charge transfer complex of the polymer with tetracyanoquinodimethane (TCNQ) was obtained in a DMSO solution.
引用
收藏
页码：1146 / 1151
页数：5
相关论文
共 14 条
  • [1] Synthesis of electron-donating polymer having vinylogous TTF in the main chain
    Inagi, Shinsuke
    Naka, Kensuke
    Iida, Daisuke
    Chujo, Yoshiki
    POLYMER JOURNAL, 2006, 38 (11) : 1146 - 1151
  • [2] Synthesis of soluble electron-donating polymers containing vinylogous TTF by oxidative dimerization of 1,4-bisdithiafulvenyl-2,5-dialkoxybenzene
    Naka, K
    Inagi, S
    Chujo, Y
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (19) : 4600 - 4608
  • [3] Synthetic Control of Spectroscopic and Photophysical Properties of Triarylborane Derivatives Having Peripheral Electron-Donating Groups
    Ito, Akitaka
    Kawanishi, Kazuyoshi
    Sakuda, Eri
    Kitamura, Noboru
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (14) : 3940 - 3953
  • [4] Synthesis, Photophysics and Redox Properties of Aza-BODIPY Dyes with Electron-Donating Groups
    Obloza, Magdalena
    Lapok, Lukasz
    Pedzinski, Tomasz
    Stadnicka, Katarzyna M.
    Nowakowska, Maria
    CHEMPHYSCHEM, 2019, 20 (19) : 2482 - 2497
  • [5] A Series of π-Extended Thiadiazoles Fused with Electron-Donating Heteroaromatic Moieties: Synthesis, Properties, and Polymorphic Crystals
    Kato, Shin-ichiro
    Furuya, Takayuki
    Nitani, Masashi
    Hasebe, Naoya
    Ie, Yutaka
    Aso, Yoshio
    Yoshihara, Toshitada
    Tobita, Seiji
    Nakamura, Yosuke
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (07) : 3115 - 3128
  • [6] Synthesis and electron-donating properties of novel norphthalocyanines containing thiacrown ether-linked tetrathiafulvalene moieties
    Guo, Jia
    Xia, Yan
    Li, Dongfeng
    Hou, Ruibin
    TETRAHEDRON LETTERS, 2016, 57 (05) : 570 - 573
  • [7] Optical properties of rod-like fluorinated polyimides and model compounds derived from diamines having high electron-donating properties
    Sato, Yoshifumi
    Yoshida, Masafumi
    Ando, Shinji
    JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2006, 19 (02) : 297 - 304
  • [8] Synthesis of Triarylamine Dyes Containing Secondary Electron-donating Groups and Application in the Dye-sensitized Solar Cells
    Liang Mao
    Xu Yingjun
    Wang Xuda
    Liu Xiujie
    Sun Zhe
    Xue Song
    ACTA CHIMICA SINICA, 2011, 69 (18) : 2092 - 2098
  • [9] Synthesis and characterization of porphyrin sensitizers with various electron-donating substituents for highly efficient dye-sensitized solar cells
    Hsieh, Chou-Pou
    Lu, Hsueh-Pei
    Chiu, Chien-Lan
    Lee, Cheng-Wei
    Chuang, Shu-Han
    Mai, Chi-Lun
    Yen, Wei-Nan
    Hsu, Shun-Ju
    Diau, Eric Wei-Guang
    Yeh, Chen-Yu
    JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) : 1127 - 1134
  • [10] Synthesis of Metallo-conjugated Copolymer with Electron Deficient Main Chain and the Formation of Polymer-Carbon Nanotube Hybrids
    Hau, King In
    Lo, Kin Cheung
    Xiong, Wenjuan
    Du, Lili
    Chan, Wai Kin
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2020, 30 (01) : 243 - 253
12