Synthesis, crystal structure, and thermal decomposition of two Co(II) complexes with NNN pyrazolyl type ligand and pseudo-halogen

被引：0

作者：

S. Öz

N. Yılmaz

C. Arıcı

I. Svoboda

M. A. Akay

O. Atakol

机构：

[1] Ahi Evran University,Faculty of Science and Arts, Department of Chemistry

[2] University of Ankara,Department Chemistry

[3] University of Hacettepe,Department of Engineering Physics

[4] Darmstadt Technical University,Material Science

来源：

Russian Journal of Coordination Chemistry | 2013年 / 39卷

关键词：

Pyrazol; Coordination Chemistry; Dmpp; Diglym; Observe Mass Loss;

D O I：

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中图分类号：

学科分类号：

摘要：

The Co(II) complexes I and II were prepared in nonaqueous solvents containing cyanate with pyrazolylpyridine ligands, namely, bis-2,6-(pyrazol-1-yl) pyridine (Pp) and bis-2,6-(3,5-dimethyl-pyrazol-1-yl) pyridine (Dmpp), respectively. These complexes were characterized with elemental analysis, IR spectroscopy, and X-ray diffraction techniques. X-ray diffraction study revealed that complex I was mononuclear and complex II was dinuclear and ionic. The ionic complex II has an octahedral cationic coordination sphere and a tetrahedral anionic coordination sphere. Thermogravimetry results showed that the thermal decomposition is starting with the carbon content of the pyrazolyl rings.

引用

页码：829 / 835

页数：6