Water-Soluble Metal—Polymer Gallium Complexes Based on Imino Derivatives of an N-Vinylpyrrolidone/N-Vinylamine Copolymer

被引:0
作者
A. G. Ivanov
I. I. Gavrilova
V. D. Krasikov
E. F. Panarin
机构
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
来源
Russian Journal of Applied Chemistry | 2019年 / 92卷
关键词
metal—polymer gallium complexes; water-soluble polymers; -vinylpyrrolidone; -vinylamine copolymers; vinyl salicylidenimines; Schiff foundations;
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学科分类号
摘要
Imino derivatives of salicylic aldehyde and a N-vinylpyrrolidone/N-vinylamine containing 15 mol % N-vinyl salicylidenimine were synthesized. Water-soluble metal—polymer complexes with a gallium content of 5 mol % were obtained by the interaction of imino derivatives with gallium(III) chloride. The structure and composition of the metal—polymer complex are confirmed by electron, vibrational, atomic emission spectroscopy with inductively coupled plasma, and by nuclear magnetic resonance spectroscopy.
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页码:1705 / 1711
页数:6
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