Metal Ion Recognition. Interaction of New Oxygen-Nitrogen Donor Macrocycles with Selected Transition and Post-Transition Metal Ions

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作者
Ronald R. Effendy
Leonard F. Fenton
Jason R. Lindoy
Brian W. Price
Tania Skelton
Gang Strixner
Allan H. Wei
机构
[1] The University of Western Australia,Department of Chemistry
[2] The University of Sydney,Centre for Heavy Metals Research, School of Chemistry
[3] James Cook University,School of Pharmacy and Molecular Sciences
关键词
discrimination; macrocycle; post-transition metal; stability; transition metal;
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摘要
As part of an ongoing investigation of the factors influencing metal ionrecognition, we have investigated structure/function relationships involvingthe metal-ion binding by three new N-benzyl-substituted, 15- and 16-membered,macrocyclic ligands incorporating N2O 3- and N 3O 3-donor sets (withthe N 3O 3-system consisting of a N 2O 3-macrocyclic ring with an attachedCH 2CH 2NCH 2C 6H 5 pendant arm). Selected solid complexes of thelatter ligand were isolated and the X-ray structures of individual Ni(II) and Ag(I) complexeswere obtained.
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页码:185 / 191
页数:6
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