Kinetics of pseudoliving free-radical copolymerization of styrene and methyl methacrylate by the reversible addition fragmentation chain-transfer mechanism

被引：0
作者：
E. V. Chernikova
A. V. Tarasenko
V. V. Yulusov
V. B. Golubev
机构：
[1] Moscow State University,Faculty of Chemistry
来源：
Polymer Science Series B | 2009年 / 51卷
关键词：
Styrene; Copolymerization; Polymer Science Series; AIBN; Homopolymerization;
D O I：
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学科分类号：
摘要：
The kinetics of copolymerization of styrene with methyl methacrylate in the presence of tert-butyl dithiobenzoate as a reversible addition fragmentation chain-transfer agent has been studied. Formation of radical intermediates has been investigated. In a wide range of monomer mixture compositions, the kinetic features of pseudoliving radical copolymerization of this monomer pair in the presence of both a low-molecular-mass reversible addition fragmentation chain-transfer (RAFT) agent and a polymer RAFT agent being formed are close to the corresponding features of the homopolymerization of styrene.
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页码：212 / 218
页数：6
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