Spin-coated kesterite CZTS thin films for photovoltaic applications

被引:0
作者
L. Majula
N. R. Mlyuka
M. E. Samiji
R. S. Bryce
D. Y. Kim
S. H. Kim
H. J. Lee
H. J. Choi
机构
[1] University of Dar es Salaam,Physics Department
[2] Heriot Watt University,School of Engineering & Physical Sciences
[3] Edinburgh Campus,School of Advanced Materials Engineering
[4] Kookmin University,undefined
来源
Journal of the Korean Physical Society | 2015年 / 67卷
关键词
Copper zinc tin-sulfide (CZTS); Thin film; Photovoltaics; Spin coating; Rapid thermal processing;
D O I
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中图分类号
学科分类号
摘要
Copper zinc tin-sulfide (CZTS) films have been widely studied over recent years due to the inherent advantages of low cost, high absorption coefficient (≥ 104 cm−1), suitable band gap (∼1.5 eV) and nontoxicity. In this work, spin coating was used to obtain CZTS films of various compositions and degrees of crystallization on glass substrates, which were then annealed at 500 °C in a N2 atmosphere by using a rapid thermal processing (RTP) furnace in order to optimize their structure. Non-stoichiometric precursors and low spinning speeds resulted in a lower sheet resistance, which is considered to be a result of lower degree of crystallization. Furthermore, the non-stoichiometric films had a high optical band gap (> 1.66 eV) whereas the band gap of the stoichiometric films (1.4 to 1.6 eV) was close to the optimal value (1.5 eV) for solar-cell applications.
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页码:1078 / 1081
页数:3
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