Fundamental concepts in chemical kinetics

被引：0

作者：

Guy Schmitz

Gábor Lente

机构：

[1] Université Libre de Bruxelles,Faculty of Applied Sciences

[2] University of Pécs,Department of General and Physical Chemistry

来源：

ChemTexts | / 6卷

关键词：

Chemical kinetics; Reaction rate; Reaction mechanism; Kinetic constants; Activation energy;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Students and young researchers will find in this article a clear and accurate presentation of fundamental concepts in chemical kinetics: reaction rates, elementary reactions and mechanisms, kinetic constants and relation to thermodynamics, and energies of activation. The discussions are based on specialized literature without going into detail and avoid misunderstandings and sometimes errors found in the general literature and on the Internet. With this aim, an original approach is sometimes adopted.

引用

共 26 条

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[3] Lente G(2018)Facts and alternative facts in chemical kinetics: remarks about the kinetic use of activities, termolecular processes, and linearization techniques Curr Opin Chem Eng 21 76-12634
[4] Gabričević M(2015)Hydrogen Isotope exchange of chlorinated ethylenes in aqueous solution: possibly a termolecular liquid phase reaction J Phys Chem A 119 12627-1914
[5] Lente G(1999)Kinetics and mechanism of the iodate-iodide reaction and other related reactions Phys Chem Chem Phys 1 1909-1246
[6] Fábián I(2017)Some considerations on the fundamentals of chemical kinetics: steady state, quasi-equilibrium, and transition state theory J Chem Educ 94 1238-3586
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[8] Perez-Benito JF(2000)O J Phys Chem A 104 5269-10717
[9] Bray WC(2015). An intermediate compound ChemTexts 1 18-6615
[10] Agreda JB(2000)Kinetic evidence for accumulation of stoichiometrically significant amounts of H J Chem Phys 112 10714-7111

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