Synthesis and structure of (tricarbollide)iodide iridium complex [(η-1-ButNH-1,7,9-C3B8H10)IrI2]2

被引：0
作者：
D. A. Loginov
A. M. Miloserdov
Z. A. Starikova
J. Holub
A. R. Kudinov
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] University of Pardubice,Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Research Center for New Inorganic Compounds and Advanced Materials
来源：
Russian Chemical Bulletin | 2013年 / 62卷
关键词：
iridium; metallacarboranes; tricarbollide;
D O I：
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学科分类号：
摘要：
Cyclooctadiene complex (η-1-ButNH-1,7,9-C3B8H10)Ir(cod) (1) was obtained by the reaction of [(7-ButNH-7,8,9-C3B8H10)]Tl with [(cod)IrCl]2 in the presence of TlPF6. The reaction of 1 with I2 gave diiodide [(η-1-ButNH-1,7,9-C3B8H10)IrI2]2 (2a). According to the X-ray diffraction data, complex 2a has a dimeric structure with two bridging iodine atoms.
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页码：1268 / 1271
页数：3
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共 83 条
[1]  
Maitlis P M(1981)undefined Chem. Soc. Rev. 10 1-undefined
[2]  
Poli R(1991)undefined Chem. Rev. 4 509-undefined
[3]  
Fish R H(1988)undefined Organometallics 7 2250-undefined
[4]  
Kim H-S(1990)undefined Organometallics 9 645-undefined
[5]  
Babin J E(1993)undefined Organometallics 12 4039-undefined
[6]  
Adams R D(1996)undefined Organometallics 15 5236-undefined
[7]  
Khattar R(2002)undefined J. Organomet. Chem. 657 115-undefined
[8]  
Naylor S(2007)undefined J. Solid State Electrochem. 11 1643-undefined
[9]  
Vargas M D(2009)undefined Russ. Chem. Bull. (Int. Ed.) 58 600-undefined
[10]  
Braga D(2011)undefined Inorg. Chem. Commun. 14 313-undefined
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