Thermochemistry of alkali metal uranoborates and their crystal hydrates

被引：0
作者：
N. G. Chernorukov
A. V. Knyazev
O. V. Kortikova
I. V. Sergacheva
机构：
[1] Lobachevsky Nizhni Novgorod State U., Nizhni Novgorod
来源：
Radiochemistry | 2003年 / 45卷 / 2期
关键词：
Physical Chemistry; Hydrate; Enthalpy; Inorganic Chemistry; Heat Capacity;
D O I：
10.1023/A:1023816822309
中图分类号：
学科分类号：
摘要：
The standard enthalpies of formation at T = 298.15 K were determined for AIBUO5·NH2O (AI = Li, Na, K, Rb, Cs). The heat capacity of crystalline NaBUO5·H 2O was determined by adiabatic vacuum calorimetry, and its thermodynamic functions were calculated. The thermodynamic characteristics of dehydration of alkali metal uranoborates were evaluated.
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页码：122 / 126
页数：4
相关论文
共 13 条
[1]  
Chernorukov N.G., Knyazev A.V., Feoktistova O.V., Zh. Neorg. Khim., 47, 2, pp. 207-211, (2002)
[2]  
Karyakin N.V., Chernorukov N.G., Knyazev A.V., Et al., Zh. Fiz. Khim., 76, 3, pp. 420-423, (2002)
[3]  
Chernorukov N.G., Suleimanov E.V., Karyakin N.V., Et al., Zh. Obshch. Khim., 72, 2, pp. 195-200, (2002)
[4]  
Codata Key Values, J. Chem. Thermodyn., 7, 1, pp. 1-3, (1975)
[5]  
Glushko V.P., Termicheskie Konstanty Veshchestv (Thermal Constants of Substances), 10 PART 1, (1981)
[6]  
Glushko V.P., Termicheskie Konstanty Veshchestv (Thermal Constants of Substances), 10 PART 2, (1981)
[7]  
Glushko V.P., Termicheskie Konstanty Veshchestv (Thermal Constants of Substances), 1 PART 1, (1974)
[8]  
Chernorukov N.G., Karyakin N.V., Usp. Khim., 64, 10, pp. 975-990, (1995)
[9]  
Knyazev A.V., Cand. Sci. (Chem.) Dissertation, (2000)
[10]  
Kelley K.K., Parks G.S., Huffman H.M., J. Phys. Chem., 33, 12, pp. 1802-1807, (1929)
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