Palladium-catalyzed regioselective cascade reaction of carbon dioxide, amines and allenes for the synthesis of functionalized carbamates

被引:0
作者
Wenfang Xiong
Ruixiang Cheng
Bowen Wu
Wanqing Wu
Chaorong Qi
Huanfeng Jiang
机构
[1] South China University of Technology,Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering
[2] South China University of Technology,State Key Lab of Luminescent Materials and Devices
来源
Science China Chemistry | 2020年 / 63卷
关键词
palladium; carbon dioxide; three-component reaction; carbamates; allenes;
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中图分类号
学科分类号
摘要
A palladium-catalyzed regioselective three-component cascade reaction of carbon dioxide, amines and allenes has been developed, providing an expedient and practical method for the construction of a range of functionalized carbamates containing dihydrobenzofuran or indole moiety in moderate to excellent yields. The broad substrate scope, good functional group tolerance and excellent chemo- and regioselectivity are the features of the transformation.
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页码:331 / 335
页数:4
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