Isopiestic Determination of Water Activity on the System LiNO3+KNO3+H2O at 273.1 and 298.1 K

被引:0
作者
Dewen Zeng
Zhaodan Wu
Yan Yao
Haijun Han
机构
[1] Chinese Academy of Sciences,Qinghai Institute of Salt Lakes
[2] Hunan South University,College of Chemistry and Chemical Engineering
来源
Journal of Solution Chemistry | 2010年 / 39卷
关键词
Water activity; Solubility; Lithium nitrate; Potassium nitrate;
D O I
暂无
中图分类号
学科分类号
摘要
Water activities in the ternary LiNO3+KNO3+H2O system and its sub-binary systems have been measured by the isopiestic method at 273.1 and 298.1 K. The measured results were treated by a Pitzer-Simonson-Clegg thermodynamic model, from which the predicted solubility isotherms were compared with the experimental results. Based on this comparison, the reliability of the measured results was discussed. The measured results help in predicting the phase diagram of the ternary system, as well as other multi-component systems based on the ternary system.
引用
收藏
页码:1360 / 1376
页数:16
相关论文
共 68 条
[21]  
Hamer W.J.(1986)Osmotic coefficients and mean activity coefficients of uni-univalent electrolytes in water at 25 °C J. Phys. Chem. 90 3009-3013
[22]  
Wu Y.C.(1992)Solubility determinations by the isopiestic method and application to aqueous lanthanide nitrates at 25 °C J. Phys. Chem. 96 3513-3520
[23]  
Rard J.A.(1992)A note about the correct water activity value of saturated potassium nitrate at 25 °C J. Phys. Chem. 96 9470-9479
[24]  
Pollio M.L.(1973)The study of the ternary systems NaNO J. Phys. Chem. 77 268-277
[25]  
Kitic D.(1999)–NH J. Solution Chem. 28 265-282
[26]  
Favetto G.J.(1996)NO J. Phys. Chem. 100 7704-7709
[27]  
Chirife J.(1968)–H Zh. Neorg. Khim. 13 2020-2026
[28]  
Karnaukhov A.S.(2010)O, KNO Chin. J. Inorg. Chem. 26 45-48
[29]  
Akerlof G.(undefined)–NH undefined undefined undefined-undefined
[30]  
Turck H.E.(undefined)NO undefined undefined undefined-undefined