Comparing the activities of catalysts in perhydro-m-terphenyl dehydrogenation

被引：12

作者：

Kalenchuk A.N. ^{[1
,2
]}

Bogdan V.I. ^{[1
,2
]}

Kustov L.M. ^{[1
,2
]}

机构：

[1] Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow

[2] Faculty of Chemistry, Moscow State University, Moscow

来源：

Catalysis in Industry | 2015年 / 7卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

catalysis; dehydrogenation; hydrogen storage; m-terphenyl; organic chemical hydrides; perhydro-m-terphenyl; platinum;

D O I：

10.1134/S2070050415010080

中图分类号：

学科分类号：

摘要：

Abstract The activities of various catalysts based on Pt, Pd, Cr, and Ni in perhydro-m-terphenyl dehydrogenation have been compared in order to develop new catalytic composites based on organic compounds for hydrogen storage. Catalytic tests have been carried out at 300-320°C in a flow reactor with an inner diameter of 10 mm. The largest amount of hydrogen released as a result of perhydro-m-terphenyl dehydrogenation to m-terphenyl is observed with the (3% Pt)/Sibunit catalyst at 320°C. The maximum selectivity toward complete dehydrogenation is 95% in this case. © Pleiades Publishing, Ltd., 2015.

引用

页码：60 / 63

页数：3

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