Synthesis, crystal structure and magnetic property of the novel dinuclear nickel(II) complex with 4-(p-methoxyphenyl)-3,5-bis(pyridine-2-yl)-1,2,4-triazole

被引：0
|
作者：
Jun Zhou
Jie Yang
Li Qi
Xuan Shen
Dunru Zhu
Yan Xu
You Song
机构：
[1] Nanjing University of Technology,College of Chemistry and Chemical Engineering
[2] Liaoning Normal University,Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering
[3] Nanjing University,State Key Laboratory of Coordination Chemistry
来源：
Transition Metal Chemistry | 2007年 / 32卷
关键词：
Triazole; MeCN; Crystal Structure Determination; Dinuclear Complex; Distorted Octahedral Geometry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel dinuclear nickel(II) complex, [Ni2(MOBPT)2Cl2(H2O)2]Cl2 · 7H2O (MOBPT = 4-(p-methoxyphenyl) −3,5-bis(pyridine-2-yl)-1,2,4-triazole), has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction methods. The crystal structure determination shows that the dinuclear Ni2N8 unit is almost planer in which each NiII ion is coordinated by four nitrogen atoms from MOBPT equatorially and a water molecule and a chloride ion axially in a distorted octahedral geometry. Magnetic measurements reveal a relatively weak antiferromagnetic exchange in the complex.
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页码：711 / 715
页数：4
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