Synthesis and reactivity of metal-containing monomers52. Synthesis and structure of TiIV-containing optically active monomers

被引：0
作者：
E. I. Klabunovskii
E. I. Karpeiskaya
G. I. Dzhardimalieva
N. D. Golubeva
A. D. Pomogailo
机构：
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Chemical Bulletin | 1999年 / 48卷
关键词：
mixed alkoxy orthotitanates; optically active monomers; transesterification; titanium-containing monomers; metal-containing polymers;
D O I：
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学科分类号：
摘要：
Optically active mixed alkoxy orthotitanates with general formula Ti(OR1)2(OR2)(OR3) (R1=Et, Bun; R2=CH2CH2OCOC(Me)=CH2; R3=menthyl, CH(Me)CH2Me, CH(Ph)CH(NHMe)Me, CH(C9H6N)(C9H14N)) were obtained for the first time by transesterification. The TiIV monomers synthesized were characterized by elemental analysis, ozonolysis, and1H and13C NMR and IR spectroscopy. Polymer products with optical activity were obtained by liquid phase radical copolymerization of TiIV-containing monomers.
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页码：1717 / 1721
页数：4
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