Migration of trimethylsilyl group in the reaction of sodium bis(trimethylsilyl)amide with bromobenzene

被引：0
作者：
A. V. Lis
I. P. Tsyrendorzhieva
A. I. Albanov
V. I. Rakhlin
M. G. Voronkov
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Branch
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
Aniline; Trimethylsilyl; Cross Peak; Aryl Halide; Bromobenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of sodium bis(trimethylsilyl)amide with bromobenzene gave a mixture of N,N-bis-(trimethylsilyl)aniline and N,2-bis(trimethylsilyl)aniline, the latter being a rearrangement product formed via 1,3-migration of trimethylsilyl group from the nitrogen atom to the ortho-carbon atom in the benzene ring.
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页码：1451 / 1453
页数：2
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