Synthesis and Crystal Structures of Two Coordination Polymers Based on a New N-Donor Aromatic Ligand

被引:0
作者
D. Zhao
F. X. Ma
R. H. Zhang
机构
[1] Henan Polytechnic University,College of Chemistry and Chemical Engineering
来源
Journal of Structural Chemistry | 2018年 / 59卷
关键词
hydrothermal; coordination polymer; X-ray diffraction; layer structure; hydrogen bond;
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中图分类号
学科分类号
摘要
Two new coordination polymers Co(C9H7N7)(SO4)(H2O) (I) and Cd(C9H6N7)2·H2O (II), where C9H7N7 is 4-(5-(1H-1,2,4-triazol-1-ylmethyl)-1,2,4-triazol-3-yl)pyridine, are synthesized through hydrothermal reactions and structurally determined by single-crystal X-ray diffraction analyses. The results reveal that compound I belongs to the triclinic space group P-1 with a 1-D chain structure, whereas compound II belongs to the monoclinic space group C2 with a 2D layer structure. Hydrogen bonds play an important role in the construction of 3D structure of the two compounds.
引用
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页码:1678 / 1683
页数:5
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