Fast electrochemical triple-interface processes at boron-doped diamond electrodes

被引：0

作者：

Frank Marken

Richard G. Compton

Christiaan H. Goeting

John S. Foord

Steven D. Bull

Stephen G. Davies

机构：

[1] Physical and Theoretical Chemistry Laboratory,

[2] Oxford University,undefined

[3] Oxford OX1 3QZ,undefined

[4] UK e-mail: frank@physchem.ox.ac.uk,undefined

[5] Dyson Perrins Laboratory,undefined

[6] Oxford University,undefined

[7] Oxford OX1 3QY,undefined

[8] UK,undefined

来源：

Journal of Solid State Electrochemistry | 2001年 / 5卷

关键词：

Key words Boron-doped diamond; Modified electrodes; Ionic liquids; Triple phase boundary; Voltammetry;

D O I：

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学科分类号：

摘要：

Two important mechanisms for electron transfer processes at boron-doped diamond electrodes involving the oxidation of tetramethylphenylenediamine (TMPD) dissolved in aqueous solution and the oxidation of tetrahexylphenylenediamine (THPD) deposited in the form of microdroplets and immersed into aqueous eletrolyte solution are reported. For TMPD, the first oxidation step in aqueous solution follows the equation:

引用

页码：88 / 93

页数：5