Vapor-liquid equilibria for the nitrogen-isobutane system

被引:0
|
作者
Guangshun Chen
Helmut Knapp
Yujun Hou
机构
[1] University of Arizona,Department of Chemical and Environmental Engineering
[2] Technical University of Berlin,Institute for Thermodynamics and Reaction Engineering
[3] Zhejiang University,Department of Chemical Engineering
来源
Journal of Solution Chemistry | 1997年 / 26卷
关键词
Nitrogen; isobutane; vapor-liquid equilibria; Henry’s law constants;
D O I
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中图分类号
学科分类号
摘要
Vapor-liquid equilibria have been investigated experimentally for the nitrogen-isobutane system at temperatures from 120 K to 220 K and at pressures up to 150 bar. Below 126.5 K, two liquid phases were observed as pressure was increased to near the vapor pressure of pure nitrogen. The equilibrium ratio of nitrogen in the binary system and the Henry’s law constants for nitrogen in isobutane were determined from experimental data. The experimental phase equilibrium data were correlated by means of the Peng-Robinson equation of state.
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页码:779 / 790
页数:11
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