Synthesis and crystal structure of an imidazolate-bridged dicopper tris(2-aminoethyl)amine complex

被引：0
|
作者：
Zhong-Lin Lu
Chun-Ying Duan
Yu-Peng Tian
Xiao-Zeng You
Hoong-Kun Fun
Boon-Chuan Yip
机构：
[1] Nanjing University,Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry
[2] University of Sains Malaysia,X
来源：
Transition Metal Chemistry | 1997年 / 22卷
关键词：
MeCN; Tren; Transition Meet; Primary Amine Group; Dicopper;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The [Cu(tren)(Im)Cu(tren)](ClO4)3·MeCN complex [tren=tris(2-aminoethyl)amine; Im=imidazolate anion] has been synthesized and characterized spectrally. The X-ray crystal structure analysis reveals that the imidazolate anion serves as a bridge to form a noncentrosymmetric dimeric structure in the complex. The co-ordination geometry about each copper(II) ion is a distorted trigonal bipyramid with three primary amine groups of the tren ligand forming the equatorial plane. The tertiary amine group and the imidazolate anion are in the axial positions.
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页码：549 / 552
页数：3
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