A study of sodium diethyldithiocarbamate oxidation at glassy carbon electrode in water and water-organic mixtures

被引：4

作者：

Basova E.M. ^{[2
]}

Ivanov V.M. ^{[1
]}

Apendeeva O.K. ^{[2
]}

Prokhorova G.V. ^{[1
]}

机构：

[1] Department of Chemistry, Moscow State University, Moscow

[2] Society and Man, Dubna International University for Nature, Moscow oblast, Dubna

来源：

Moscow University Chemistry Bulletin | 2013年 / 68卷 / 2期

关键词：

glassy carbon electrode; oxidation; sodium diethyldithiocarbamate; voltammetry;

D O I：

10.3103/S0027131413020028

中图分类号：

学科分类号：

摘要：

The oxidation of sodium diethyldithiocarbamate at a glassy carbon electrode in water and water-organic mixtures in the presence of KCl and NaOH is investigated. Using cyclic square-wave voltammetry and rotated electrode voltammetry it is shown that, in water and water-ethanol mixtures, the electrode reaction is irreversible. In the case of KCl water solution, the oxidation reaction involves one electron. In the case of KCl in a water-ethanol mixture, two electrons are involved. The possible oxidation mechanism is discussed. © 2013 Allerton Press, Inc.

引用

页码：87 / 92

页数：5