Modulation of the lower critical solution temperature of 2-Alkyl-2-oxazoline copolymers

被引：0
|
作者：
Stephan Huber
Rainer Jordan
机构：
[1] Technische Universität München,Wacker
来源：
Colloid and Polymer Science | 2008年 / 286卷
关键词：
Poly(2-oxazoline); LCST; Thermo-responsive polymer; Living cationic polymerization; Copolymer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Living cationic copolymerization of 2-isopropyl-2-oxazoline with 2-n-propyl-, 2-n-butyl-, and 2-n-nonyl-2-oxazoline results in gradient copolymers of defined composition, narrow molar mass distributions (PDI = 1.09–1.3), and defined overall degree of polymerization, set to n = 25 for all polymers. The introduction of monomer units of stronger amphiphilic character results in a systematic decrease of the lower critical solution temperature (LCST). The LCST modulation can be controlled by the choice of the comonomer as well as the comonomer ratio and was tuned in the temperature range from 46 to 9 °C.
引用
收藏
页码：395 / 402
页数：7
相关论文
共 50 条
  • [1] Modulation of the lower critical solution temperature of 2-Alkyl-2-oxazoline copolymers
    Huber, Stephan
    Jordan, Rainer
    COLLOID AND POLYMER SCIENCE, 2008, 286 (04) : 395 - 402
  • [2] Thermoresponsive behavior of polyrotaxanes based on α-cyclodextrins threaded on poly(2-alkyl-2-oxazoline)-poly(ethylene glycol)-poly (2-alkyl-2-oxazoline) triblock copolymers
    Kirila, T. U.
    Golovina, M. A.
    Kurlykin, M. P.
    Filippov, A. P.
    Tenkovtsev, A. V.
    EUROPEAN POLYMER JOURNAL, 2023, 196
  • [3] Oligo(2-alkyl-2-oxazoline)-based graft copolymers for marine antifouling coatings
    Guazzelli, Elisa
    Santarlasci, Luca
    Oliva, Matteo
    Pretti, Carlo
    Romio, Matteo
    Glisenti, Antonella
    Benetti, Edmondo M.
    Martinelli, Elisa
    EUROPEAN POLYMER JOURNAL, 2023, 190
  • [4] Aggregation behavior of amphiphilic poly(2-alkyl-2-oxazoline) diblock copolymers in aqueous solution studied by fluorescence correlation spectroscopy
    Tune B. Bonné
    Karin Lüdtke
    Rainer Jordan
    Petr Štěpánek
    Christine M. Papadakis
    Colloid and Polymer Science, 2004, 282 : 833 - 843
  • [5] Aggregation behavior of amphiphilic poly(2-alkyl-2-oxazoline) diblock copolymers in aqueous solution studied by fluorescence correlation spectroscopy
    Bonné, TB
    Lüdtke, K
    Jordan, R
    Stepánek, P
    Papadakis, CM
    COLLOID AND POLYMER SCIENCE, 2004, 282 (08) : 833 - 843
  • [6] Aggregation behavior of amphiphilic poly(2-alkyl-2-oxazoline) diblock copolymers in aqueous solution studied by fluorescence correlation spectroscopy
    Tune B. Bonné
    Karin Lüdtke
    Rainer Jordan
    Petr Štěpánek
    Christine M. Papadakis
    Colloid and Polymer Science, 2004, 282 : 1425 - 1425
  • [7] Revisiting the Crystallization of Poly(2-alkyl-2-oxazoline)s
    Demirel, A. Levent
    Guner, Pinar Tatar
    Verbraeken, Bart
    Schlaad, Helmut
    Schubert, Ulrich S.
    Hoogenboom, Richard
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2016, 54 (07) : 721 - 729
  • [8] Polysaccharide-graft-poly(2-alkyl-2-oxazoline) hybrid copolymers: Versatile materials for bioapplications
    Hruby, Martin
    Loukotova, Lenka
    Rabyk, Mariia
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [9] Poly(2-alkyl-2-oxazoline)s: Bulk crystallization and solution self-assembly
    Demirel, A. Levent
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [10] Self-Assembly of Poly(2-alkyl-2-oxazoline)s by Crystallization in Ethanol-Water Mixtures Below the Upper Critical Solution Temperature
    Diehl, Christina
    Dambowsky, Ina
    Hoogenboom, Richard
    Schlaad, Helmut
    MACROMOLECULAR RAPID COMMUNICATIONS, 2011, 32 (21) : 1753 - 1758
12345