Complexes of iron(III) salen and saloph Schiff bases with bridging 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine and 2,4,6-tris(4-carboxyphenylimino-4′-formylphenoxy)-1,3,5-triazine

被引：0
|
作者：
Ziya Erdem Koc
H. Ismet Ucan
机构：
[1] Selcuk University,Department of Chemistry
来源：
Transition Metal Chemistry | 2007年 / 32卷
关键词：
Triazine; Salen; Transition Meet; AcOEt; Salicylidene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Four new trinuclear Fe(III) complexes involving tetradenta Schiff bases N,N1-bis(salicylidene) ethylenediamine-(salenH2) or bis(salicylidene)-o-phenylenediamine-(salophH2) with 2,4,6-tris(2,5-dicarboxyphenylimino-4-formylphenoxy)-1,3,5-triazine (DCPI-TRIPOD) or 2,4,6-tris(4-carboxyphenylimino-4′-formylphenoxy)-1,3,5-triazine (CPI-TRIPOD) have been synthesized and characterized by means of elemental analysis carrying out 1H-n.m.r., i.r. spectroscopy, thermal analyses and magnetic susceptibility measurements. The complexes can also be characterized as high-spin distorted octahedral FeIII bridged by carboxylic acids. The tricarboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange.
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页码：597 / 602
页数：5
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