Physico-chemical investigations and thermal degradation studies of 4-ethylpiperazine-1-carbodithioic acid complexes of copper(II)

被引：0
作者：
Shashi B. Kalia
Manjeet Sharma
Monika Bharti
Dharvinder Kumar
机构：
[1] Himachal Pradesh University,Department of Chemistry
来源：
Journal of Thermal Analysis and Calorimetry | 2017年 / 130卷
关键词：
4-Ethylpiperazine-1-carbodithioic acid; Copper(II); IR; Cyclic voltammetry; UV–Visible; Magnetic moment; TG/DSC;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Synthesis of copper(II) carbodithioates, viz.[Cu(4-EtPipzcdtH)2]Xn (4-EtPipzcdtH = 4-ethylpiperazine-1-carbodithioic acid, X = Cl, ClO4, NO3 and CH3COO when n = 2; X = SO4 when n = 1), has been carried out. These have been investigated by FT-IR, UV–Visible spectral and room temperature magnetic (1.59–1.72 B.M.) studies. 1H NMR and ESMS of [Cu(4-EtPipzcdtH)2](ClO4)2 and [Cu(4-EtPipzcdtH)2]Cl2 further supported their formation. Based on characterization techniques chelating bidentate mode of coordination of ligand, 4-EtPipzcdtH with four coordination around copper(II) was proposed. Copper(II) carbodithioates with Cl, ClO4, NO3 and CH3COO as counter anions exhibited 1:2 electrolytic behaviour, while 1:1 electrolytic behaviour was observed for complex with SO4 as counter anion. Cyclic voltammetry study conducted on complexes, viz. [Cu(4-EtPipzcdtH)2]Xn (X = Cl, ClO4, NO3 when n = 2; X = SO4 when n = 1) revealed redox process due to CuII/CuIII couple. Complexes were also studied using non-isothermal techniques (TG/DSC). The complexes [Cu(4-EtPipzcdtH)2]X2 (X = ClO4, NO3) showed oxidative thermal decomposition behaviour.
引用
收藏
页码：1095 / 1103
页数：8
相关论文
共 108 条
  • [11] Ghammamy S(2006)] J Braz Chem Soc 17 107-112
  • [12] Ashuri S(2004)Hg Thermochim Acta 411 139-148
  • [13] Aghbolagh ZS(2013)Synthesis and characterization of 2-amino pyridine dithiocarbamate ligand and it’s Cu(II), Co(II) metal complexes Bull Chem Soc Ethiop 27 77-84
  • [14] Kalia SB(2007)Thermal studies of Zn(II), Cd(II) and Hg(II) complexes of some N-alkyl-N-phenyl-dithiocarbamates Turk J Chem 31 435-442
  • [15] Kumar D(2011)Thermal decomposition of transition metal dithiocarbamates Malays J Anal Sci 15 106-112
  • [16] Sharma M(2002)Template synthesis of symmetrical transition metal dithiocarbamates J Serbian Chem Soc 67 123-126
  • [17] Christopher J(2006)Application of thermogravimetric analysis for characterisation of bisdithiocarbamate of urea and its copper (II) complex Polyhedron 25 3366-3378
  • [18] Chohan ZH(2005)Synthesis, characterization and antibacterial studies of metal complexes of sulfadiazine with N-alkyl-N-phenyldithiocarbamate J Appl Spectrosc 72 37-42
  • [19] Sumrra SH(2006)Preparation, spectroscopy, antimicrobial assay and x-ray structure of dimethyl bis-(4-methylpiperidine dithiocarbamato-S, S)-tin(IV) Ind J Chem 45 1400-1404
  • [20] Youssoufi MH(2000)Synthesis and characterization of diphenyltin(IV) dithiocarbamate compounds Transit Met Chem 25 69-72
12345678910