EPR Spectroscopy of Impurity Ytterbium Ions in Synthetic Forsterite Single Crystals

被引:0
作者
V. F. Tarasov
A. A. Sukhanov
E. V. Zharikov
K. A. Subbotin
D. A. Lis
机构
[1] Federal Research Center “Kazan Scientific Center of RAS”,Zavoisky Physical‑Technical Institute
[2] Russian Academy of Sciences,Prokhorov General Physics Institute
[3] Mendeleev University of Chemical Technology,undefined
来源
Applied Magnetic Resonance | 2022年 / 53卷
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摘要
Continuous wave and pulse X-band electron paramagnetic resonance spectroscopy are used to determine structure, magnetic and relaxation properties of paramagnetic centers formed by impurity ytterbium ions in forsterite (Mg2SiO4) single crystals. It is found that Yb3+ ions substitute Mg2+ ions both as single ions and as dimeric associates with nearby magnesium vacancy. For all ytterbium centers, magnetic properties are characterized by the strong easy plane anisotropy. Measurements in temperature range 5–15 K showed that spin–lattice relaxation of the Yb3+ ions in Mg2SiO4 is due to joint action of direct one-phonon process, Raman two-phonon process and resonance two-phonon Aminov–Orbach process.
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页码:1211 / 1226
页数:15
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