Kinetics of hydrogen peroxide decomposition in the presence of binuclear complexes of cobalt(II) with 1,4-piperazine-bis(carbothiosulfene diethylamide)

被引：0

作者：

D. G. Chikhichin

V. A. Kotseruba

O. A. Levchenko

G. N. Khitrich

I. I. Seifullina

G. L. Kamalov

机构：

[1] A. V. Bogatskii Physico-Chemical Institute,

[2] National Academy of Sciences of Ukraine,undefined

[3] I. I. Mechnikov Odesa National University,undefined

来源：

Theoretical and Experimental Chemistry | 2011年 / 47卷

关键词：

thiocarbamoyl sulfenamides; cobalt(II) complexes; ligand; hydrogen peroxide; decomposition kinetics; catalyst; isokinetic relationship;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

We have obtained complexes of Co(II) with 1,4-piperazine-bis(carbothiosulfene diethylamide) (L) of composition [Co2LX4] (X = Cl, Br, I, NCS). We discuss the characteristic features of the decomposition kinetics for H2O2 in the presence of these complexes and the effect of the acido ligands X on their catalytic activity. We have observed isokinetic relationships between the activation parameters and the reaction rate constants. We show that the values of the parameters α and β in the Edwards equation to a considerable extent are due to the composition of the complexes and the ratio [H2O2]0/[Cat]0.

引用

页码：115 / 122

页数：7

共 18 条

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