Hydrothermal synthesis and novel two-dimensional architecture with fluorescent properties constructed using 2-bromo-1,4-benzenedicarboxylate

被引：0
作者：
Ai-Qing Ma
Long-Guan Zhu
机构：
[1] Zhejiang University,Department of Chemistry
来源：
Transition Metal Chemistry | 2004年 / 29卷
关键词：
Physical Chemistry; Crystal Structure; Inorganic Chemistry; Phen; Hydrothermal Synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A novel two-dimensional complex, [Cu(bbdc)(phen)]·(H2O)(bbdc = 2-bromo-1,4-benzenedicarboxylate dianion; phen = 1,10-phenanthroline), has been synthesized and structurally characterized by single crystal X-ray analysis. The crystal structure consists of infinite chains of [Cu2(μ4-bbdc)]2+ units connected by bis-monodentate bbdc ligands, the coordination mode of which [μ4-bbdc] is very rare in the phenyldicarboxylate complexes. The substituent group of bbdc is believed to be the growth key of this coordination network.
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页码：329 / 331
页数：2
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