Synthesis of 3-alkyl(aryl)thietanes

被引：0

作者：

S. E. Shevchenko

N. P. Volynskii

机构：

[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis

来源：

Petroleum Chemistry | 2008年 / 48卷

关键词：

Propanediol; Petroleum Chemistry; Sulfonyl Chloride; Lithium Aluminum Hydride; Organic Sulfur Compound;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A preparative procedure for the synthesis of thietanes bearing alkyl substituents in the β-position was developed. Using this procedure, 3-substituted thietanes can be obtained in four steps with an ultimate yield of > 50%. 3-R-thietanes (where R = CH3, C4H9, C5H11, C6H13, C6H5) and the corresponding sulfoxides and sulfones were synthesized and examined. The feasibility of preparation of gem-3,3-substituted thietanes was exemplified by the synthesis of 3,3-dihexylthietane.

引用

页码：123 / 128

页数：5

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