Synthesis of 3-alkyl(aryl)thietanes

被引：0
作者：
S. E. Shevchenko
N. P. Volynskii
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Petroleum Chemistry | 2008年 / 48卷
关键词：
Propanediol; Petroleum Chemistry; Sulfonyl Chloride; Lithium Aluminum Hydride; Organic Sulfur Compound;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A preparative procedure for the synthesis of thietanes bearing alkyl substituents in the β-position was developed. Using this procedure, 3-substituted thietanes can be obtained in four steps with an ultimate yield of > 50%. 3-R-thietanes (where R = CH3, C4H9, C5H11, C6H13, C6H5) and the corresponding sulfoxides and sulfones were synthesized and examined. The feasibility of preparation of gem-3,3-substituted thietanes was exemplified by the synthesis of 3,3-dihexylthietane.
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页码：123 / 128
页数：5
相关论文
共 17 条
  • [1] Clapperton B. K.(1989)undefined J. Chem. Ecol. 15 291-undefined
  • [2] Minot E. O.(2000)undefined J. Organomet. Chem. 596 115-undefined
  • [3] Crump D. R.(2003)undefined Tetrahedron Lett. 44 6519-undefined
  • [4] Adams R. D.(1970)undefined J. Org. Chem. 35 3657-undefined
  • [5] Perrin J. L.(1966)undefined Chem. Rev. 66 341-undefined
  • [6] Queisser J. A.(2007)undefined Neftekhimiya 47 125-undefined
  • [7] Rogers R. D.(2003)undefined Neftekhimiya 43 380-undefined
  • [8] Romashin Y. N.(undefined)undefined undefined undefined undefined-undefined
  • [9] Liu T. H.(undefined)undefined undefined undefined undefined-undefined
  • [10] Hill B. T.(undefined)undefined undefined undefined undefined-undefined
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