Secondary metabolites from species of the biocontrol agent Trichoderma

被引:364
作者
Reino J.L. [1 ]
Guerrero R.F. [1 ]
Hernández-Galán R. [1 ]
Collado I.G. [1 ]
机构
[1] Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Puerto Real, Cádiz 11510
关键词
Biological control; Metabolites; Phytopathogen; Toxins; Trichoderma;
D O I
10.1007/s11101-006-9032-2
中图分类号
学科分类号
摘要
Trichoderma species are free-living fungi that are highly interactive in root, soil and foliar environments and have been used successfully in field trials to control many crop pathogens. Structural and biological studies of the metabolites isolated from Trichoderma species are reviewed. This review, encompassing all the literature in this field up to the present and in which 269 references are cited, also includes a detailed study of the biological activity of the metabolites, especially the role of these metabolites in biological control mechanisms. Some aspects of the biosynthesis of these metabolites and related compounds are likewise discussed. © 2007 Springer Science+Business Media B.V.
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收藏
页码:89 / 123
页数:34
相关论文
共 181 条
[1]  
Abe N., Murata T., Hirota A., Novel DPPH radical scavengers, bisorbicillinol and demethyltrichodimerol, from a fungus, Biosci Biotechnol Biochem, 62, pp. 661-666, (1998)
[2]  
Abe N., Murata T., Hirota A., Novel oxidized sorbicillin dimers with 1,1-diphenyl-2-picrylhydrazyl radical scavenging activity from a fungus, Biosci Biotechnol Biochem, 62, pp. 2120-2126, (1998)
[3]  
Abe N., Murata T., Yamamoto K., Hirota A., Bisorbibetanone, a novel oxidized sorbicillin dimer, with 1,1-diphenyl-2-picrylhydrazyl radical scavenging activity from a fungus, Tetrahedron Lett, 40, pp. 5203-5206, (1999)
[4]  
Abe N., Yamamoto K., Hirota A., Novel fungal metabolites, demethylsorbicillin and oxosorbicillinol, isolated from Trichoderma sp. USF-2690, Biosci Biotechnol Biochem, 64, pp. 620-622, (2000)
[5]  
Abe N., Sugimoto O., Tanji K., Hirota A., Identification of the quinol metabolite "sorbicillinol", a key intermediate postulated in bisorbicillinoid biosynthesis, J Am Chem Soc, 122, pp. 12606-12607, (2000)
[6]  
Abe N., Sugimoto O., Arakawa T., Tanji K., Hirota A., Sorbicillinol, a key intermediate of bisorbicillinoid biosynthesis in Trichoderma sp. USF-2690, Biosci Biotechnol Biochem, 65, pp. 2271-2279, (2001)
[7]  
Abe N., Arakawa T., Hirota A., The biosynthesis of bisvertinolone: Evidence for oxosorbicillinol as a direct precursor, Chem Commun, 3, pp. 204-205, (2002)
[8]  
Abe N., Arakawa T., Yamamoto K., Hirota A., Biosynthesis of bisorbicillinoid in Trichoderma sp. USF-2690
[9]  
Evidence for the biosynthetic pathway, via sorbicillinol, of sorbicillin, bisorbicillinol, bisorbibutenolide, and bisorbicillinolide, Biosci Biotechnol Biochem, 66, pp. 2090-2099, (2002)
[10]  
Abrahamsson S., Nilsson B., Molecular structure of trichodermin, Acta Chem Scand, 20, pp. 1044-1052, (1966)