Arylation of 6H-dibenzo[c,e][1,2λ5]oxaphosphinine 6-oxide

被引:0
作者
I. P. Beletskaya
E. G. Neganova
Yu. A. Veits
机构
[1] Lomonosov Moscow State University,Faculty of Chemistry
来源
Russian Journal of Organic Chemistry | 2004年 / 40卷
关键词
Nickel; Phosphorus; Organic Chemistry; Catalysis; Iodide;
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摘要
Arylation and alkylation of 6H-dibenzo[c,e][1,2λ5]oxaphosphinine 6-oxide at the phosphorus atom was accomplished. Tetrafluoro-4-pyridyl fragment was introduced via reaction of 6-trimethylsiloxy-6H-dibenzo[c,e][1,2]oxaphosphinine with pentafluoropyridine. The arylation of the title compound with aryl iodides containing both electron-acceptor and electron-donor substituents was effected under catalysis by palladium or nickel complexes.
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页码:1782 / 1786
页数:4
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