Crystal structure of indium(III) schiff base complex

被引：5

作者：

Swamy G.Y.S.K. ^{[1
]}

Ravikumar K. ^{[1
]}

机构：

[1] Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology

来源：

Journal of Structural Chemistry | 2011年 / 52卷 / 1期

关键词：

Crystal structure; Hydrogen bonding; Metal complex; Schiff base; X-ray diffraction;

D O I：

10.1134/S0022476611010306

中图分类号：

学科分类号：

摘要：

The title compound [In(C22H30N4O 4)]Cl (I) bis[(N-salicylidene-N'-(2-hydroxyethyl)ethyleneediamine) indium(III) chloride is prepared, and its crystal structure is determined by single crystal X-ray diffraction at room temperature. The complex crystallizes in the monoclinic space group P21/n, a = 9.9704(6) Å, b = 24.9554(15) Å, c = 10.5707(6) Å, β = 116.46(2)°, V = 2354.6(2), Z = 4. The X-ray analysis reveals that the InIII ion is surrounded by four nitrogen and two oxygen atoms from two ligands leading to a distorted octahedral geometry. The molecule has the form of tongs at a junction point with the metal. Five membered rings adopt envelope conformation. In the crystal structure, the molecules are linked via N-H...Cl, O-H...O, O-H...Cl, and C-H...Cl intermolecular interactions. The structure is further stabilized by C-H...π (arene) interactions. © 2011 by G. Y. S. K. Swamy and K. Ravikumar.

引用

页码：208 / 211

页数：3

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