Rhodium‐catalyzed silylative coupling of olefins with vinylsilanes

被引：0
|
作者：
Bogdan Marciniec
Edyta Walczuk‐Guściora
Cezary Pietraszuk
机构：
来源：
Catalysis Letters | 1998年 / 55卷
关键词：
rhodium‐complex catalysis; silylative coupling of olefins; vinylsilane;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
RhH(CO)(PPh33 appeared to be a very effective catalyst for disproportionation of vinylsilanes and their co‐disproportionation with styrene and 1‐decene. The insertion of vinylsilane (or bis(silyl)ethene) into the Rh–H bond followed by β‐silyl transfer to form a Rh–Si bond and elimination of ethylene (or vinylsilane), in combination with a MS study of the product of the reaction of styrene‐d8 with vinylsilane and well‐known insertion of alkene into the Rh–Si bond accounts for a non‐metallacarbene mechanism of a new rhodium‐catalyzed silylation of olefins with vinylsilanes.
引用
收藏
页码：105 / 112
页数：7
相关论文
共 50 条
  • [31] Hydroformylation and related reactions of vinylsilanes catalyzed by siloxide complexes of rhodium(I) and iridium(I)
    Mieczynska, E
    Trzeciak, AM
    Ziolkowski, JJ
    Kownacki, I
    Marciniec, B
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 237 (1-2) : 246 - 253
  • [32] Rhodium(III)-catalyzed synthesis of indanones via C-H activation of phenacyl phosphoniums and coupling with olefins
    Li, Yunyun
    Yang, Xifa
    Kong, Lingheng
    Li, Xingwei
    ORGANIC CHEMISTRY FRONTIERS, 2017, 4 (11): : 2114 - 2118
  • [33] Phosphine-stabilized, oxide-supported rhodium catalysts for highly efficient silylative coupling reactions
    Tsukada, Shinji
    Wada, Kenji
    Miura, Hiroki
    Hosokawa, Saburo
    Abe, Ryu
    Inoue, Masashi
    RESEARCH ON CHEMICAL INTERMEDIATES, 2015, 41 (12) : 9575 - 9586
  • [34] HYDROISOMERIZATION OF OLEFINS CATALYZED BY TRIS(TRIPHENYLPHOSPHINE)RHODIUM (I) HALIDES
    BOND, GC
    HILLYARD, RA
    DISCUSSIONS OF THE FARADAY SOCIETY, 1968, (46): : 20 - &
  • [35] Functionalization of octavinylsilsesquioxane by ruthenium-catalyzed silylative coupling versus cross-metathesis
    Itami, Y
    Marciniec, B
    Kubicki, M
    CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (05) : 1239 - 1248
  • [36] Hydroformylation of olefins catalyzed by rhodium complexes with phosphinitecalix[4]arenes
    Karakhanov, E. A.
    Kardasheva, Yu. S.
    Runova, E. A.
    Terenina, M. V.
    Shadrova, A. Yu.
    PETROLEUM CHEMISTRY, 2007, 47 (05) : 340 - 344
  • [37] Influence of an additional gas on the rhodium-catalyzed hydroformylation of olefins
    Caporali, M
    Frediani, P
    Piacenti, F
    Salvini, A
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 204 : 195 - 200
  • [38] Research progress of olefins asymmetric hydrogenation catalyzed by rhodium catalysts
    Jiang, Lihong (jlh65@163.com), 1600, Materials China (35):
  • [39] Hydroformylation of olefins catalyzed by transient montomorillonite rhodium (II) catalyst
    Halligudi, SB
    INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 1997, 4 (03) : 150 - 154
  • [40] MECHANISTIC STUDIES ON THE RHODIUM COMPLEX CATALYZED HYDROFORMYLATION REACTION OF OLEFINS
    TRZECIAK, AM
    ZIOLKOWSKI, JJ
    JOURNAL OF MOLECULAR CATALYSIS, 1983, 19 (01): : 41 - 55
12345