A 1H and 13C NMR and UV Study of the State of Hydroxyacetone in Aqueous Solutions

被引：0
|
作者：
G. K. Glushonok
T. G. Glushonok
L. A. Maslovskaya
O. I. Shadyro
机构：
[1] Belarussian State University,Research Institute of Physicochemical Problems
来源：
Russian Journal of General Chemistry | 2003年 / 73卷
关键词：
Spectroscopy; Aqueous Solution; Hydrated; Carbonyl; Hydrated Form;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The state of hydroxyacetone in neutral aqueous solutions was studied by 1H and 13C NMR and UV spectroscopy. In the concentration range 0.1-1.41 M, 96-98% of hydroxyacetone exists in the carbonyl form. The content of the hydrated form of hydroxyacetone is 2-4%. No dimeric and polymeric species were detected.
引用
收藏
页码：1027 / 1031
页数：4
相关论文
共 50 条
  • [1] A 1H and 13C NMR and UV study of the state of hydroxyacetone in aqueous solutions
    Glushonok, GK
    Glushonok, TG
    Maslovskaya, LA
    Shadyro, OI
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (07) : 1027 - 1031
  • [2] Assignments of the 1H and 13C NMR Spectra of Anhydroerythyromycin A in Organic and Aqueous Solutions
    Magn Res Chem, 10 (837):
  • [3] 1H and 13C NMR study of perdeuterated pyrazoles
    Jimeno, ML
    Jagerovic, N
    Elguero, J
    Junk, T
    Catallo, WJ
    SPECTROSCOPY-AN INTERNATIONAL JOURNAL, 1997, 13 (04): : 291 - 294
  • [4] The tautomerism of Omeprazole in solution:: a 1H and 13C NMR study
    Claramunt, RM
    López, C
    Alkorta, I
    Elguero, J
    Yang, R
    Schulman, S
    MAGNETIC RESONANCE IN CHEMISTRY, 2004, 42 (08) : 712 - 714
  • [5] A 13C and 1H NMR analysis of perfumes
    Talzi, VP
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2006, 79 (01) : 107 - 116
  • [6] 1H and 13C NMR study of copteroside E derivatives
    Cerda-García-Rojas, CM
    Zamorano, G
    Chávez, MI
    Catalán, CAN
    Joseph-Nathan, P
    MAGNETIC RESONANCE IN CHEMISTRY, 2000, 38 (07) : 494 - 499
  • [7] 1H and 13C NMR characteristics of β-blockers
    Zielinska-Pisklak, Monika Agnieszka
    Pisklak, Dariusz Maciej
    Wawer, Iwona
    MAGNETIC RESONANCE IN CHEMISTRY, 2011, 49 (05) : 284 - 290
  • [8] Assignment of the 1H and 13C NMR of tocotrienois
    Ohnmacht, Stephan
    West, Ryan
    Sirnionescu, Razvan
    Atkinson, Jeffrey
    MAGNETIC RESONANCE IN CHEMISTRY, 2008, 46 (03) : 287 - 294
  • [9] A 13C and 1H NMR analysis of perfumes
    V. P. Talzi
    Russian Journal of Applied Chemistry, 2006, 79 : 107 - 116
  • [10] ~1H and 13C NMR Studies on M (EGTA) Complexes in Aqueous Solution
    张善荣
    任吉民
    吴亦洁
    刘爱琢
    裴奉奎
    ChineseScienceBulletin, 1993, (22) : 1880 - 1883
12345