Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

被引：5

作者：

Petrov, Pavel A. ^{[1
,2
]}

Naumov, Dmitry Yu. ^{[1
]}

Sukhikh, Taisiya S. ^{[1
,2
]}

Konchenko, Sergey N. ^{[1
,2
]}

Gomez-Garcia, Carlos J. ^{[3
]}

Llusar, Rosa ^{[4
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, Lavrentiev Av 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogov St 2, Novosibirsk 630090, Russia

[3] Univ Valencia, Inst Ciencia Mol ICMol, C Catedrat Jose Beltran 2, Paterna 46980, Valencia, Spain

[4] Univ Jaume 1, Dept Quim Fis & Analit, Av Sos Baynat S-N, Castellon de La Plana 12071, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 16期

基金：

俄罗斯基础研究基金会;

关键词：

X-RAY-STRUCTURE; MIXED-METAL CLUSTER; SHARED DOUBLE CUBE; MOLYBDENUM; COMPLEXES; DERIVATIVES; REACTIVITY; SINGLE; MO;

D O I：

10.1039/c7nj01217a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron precise [Mo-3(mu(3)-S)(mu-S)(3)(diphos)(3)Br-3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo-3(GaBr)(mu(3)-S)(4)-(diphos)(3)Br-3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

引用

页码：7849 / 7852

页数：4

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