Complex formation of silver(i) ions with a glucosinolate derivative: structural and mechanistic insights into myrosinase-mimicking C-S bond cleavage

被引：0

作者：

Alba, Laurenzo D. V. ^{[1
,2
]}

Hatanaka, Tsubasa ^{[1
]}

Franco, Francisco C., Jr. ^{[2
]}

Nojiri, Masaki ^{[1
]}

Noel, Marissa G. ^{[2
]}

Funahashi, Yasuhiro ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, 1-1 Machikaneyama, Toyonaka, Osaka 5600043, Japan

[2] De Salle Univ Manila, Dept Chem, 2401 Taft Ave, Manila 0922, Philippines

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 24期

关键词：

CRYSTAL-STRUCTURE; X-RAY; DECOMPOSITION; RESOLUTION; SHOWS;

D O I：

10.1039/d1dt00695a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of an unprecedented silver complex of O-acetylsinigrin has shown chelating bonds of the sulfated thiohydroximate and an eta(2)-bond of the ethylene moiety with Ag(i). Mechanistic studies on the formation and decomposition of the complex by the H-1 NMR measurements and theoretical calculations with the DFT method indicated relevance to the glucosinolate degradation in biological systems.

引用

页码：8292 / +

页数：6

共 21 条

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