Variations in the Spatial Distribution of Sonoluminescing Bubbles in the Presence of an Ionic Surfactant and Electrolyte

被引:26
作者
Lee, Judy [1 ]
Vakarelski, Ivan U. [2 ]
Yasui, Kyuichi [1 ]
Tuziuti, Toru [1 ]
Kozuka, Teruyuki [1 ]
Towata, Atsuya [1 ]
Iida, Yasuo [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Moriyama Ku, Nagoya, Aichi 4638560, Japan
[2] Inst Chem & Engn Sci, Singapore 627833, Singapore
关键词
SONOCHEMICAL EFFICIENCY; ULTRASONIC FREQUENCY; DYNAMIC FORCES; ACTIVE ZONES; COALESCENCE; SOLUTES; ENHANCEMENT; GROWTH; DROPS; AFM;
D O I
10.1021/jp907329z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It has been established that the addition of sodium dodecylsulfate (SDS) to water to a concentration of 1 mM increased the integrated sonoluminescence (SL) intensity to a maximum. Moreover, further increase in the SDS concentration to 10 mM decreased the SL intensity to a level comparable to that obtained for water. Photographic images of water and 10 mM SDS have revealed a localized distribution of SL bubbles near the liquid Surface. For 1 mM SDS, a homogeneous distribution of SL bubbles was observed throughout the liquid. In this Study, a comprehensive investigation was performed to determine the variations in the spatial distribution of SL bubbles as a function of SDS concentration, with and without the addition of sodium chloride (NaCl). It was found that the integrated SL intensity passed through a local Minimum as the distribution of SL bubbles transformed from an isolated to a homogeneous distribution at 0.25 and 2.4 mM SDS. Similar transformations in the spatial distribution of SL bubbles within these SDS solutions were also observed upon the addition of a few millimolar NaCl. These variations in the spatial distribution of SL bubbles in aqueous solutions containing an ionic surfactant and electrolyte were believed to be the result of changes in the coalescence stability of bubbles, the attenuation of the acoustic wave, and the standing wave ratio.
引用
收藏
页码:2572 / 2577
页数:6
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