Photoinduced vitrification near the surfaces of single crystals of azobenzene-based molecular materials with glass-forming ability

被引：28

作者：

Nakano, Hideyuki ^{[1
]}

Seki, Shu ^{[1
]}

Kageyama, Hiroshi ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 28期

关键词：

Photoinduced vitrification was observed to take place near the; surfaces of the single crystals of azobenzene-based molecular; materials with glass-forming ability. The phenomenon was; caused by repetition of the trans-cis and cis-trans isomerization; reactions and hence can be regarded as a kind of photomechanical; effect; RELIEF GRATING FORMATION; PHOTOIRRADIATION; POLYMERS;

D O I：

10.1039/b926570h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoinduced vitrification was observed to take place near the surfaces of the single crystals of azobenzene-based molecular materials with glass-forming ability. The phenomenon was caused by repetition of the trans-cis and cis-trans isomerization reactions and hence can be regarded as a kind of photomechanical effect. © the Owner Societies 2010.

引用

页码：7772 / 7774

页数：3

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