A fluorinated masked o-benzoquinone

被引：8
|
作者：
Patrick, TB [1 ]
Yu, H [1 ]
Taylor, D [1 ]
Gorrell, K [1 ]
机构：
[1] So Illinois Univ, Dept Chem, Edwardsville, IL 62026 USA
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 12期
基金：
美国国家科学基金会;
关键词：
fluorine; Diels-Alder; oxidation; bicyclic compounds;
D O I：
10.1016/j.jfluchem.2004.06.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A fluorinated masked o-benzoquinone has been prepared by oxidation 4-fluoro-2-methoxyphenol in methanol with phenyliodine diacetate. The fluorinated diene reacts in situ in normal Diels-Alder reactions with various dienophiles. The sequence provides new fluorinated building blocks for the synthesis of a variety of fluorinated compounds. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：1965 / 1966
页数：2
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