Spin Divergence Induced by Exohedral Modification: ESR Study of Sc3C2@C80 Fulleropyrrolidine

被引：60
作者：
Wang, Taishan [1 ]
Wu, Jingyi [1 ]
Xu, Wei [1 ]
Xiang, Junfeng [1 ]
Lu, Xin [2 ]
Li, Bao [1 ]
Jiang, Li [1 ]
Shu, Chunying [1 ]
Wang, Chunru [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
[2] Xiamen Univ, Dept Chem, Ctr Theoret Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 10期
关键词：
carbides; endohedral fullerenes; EPR spectroscopy; exohedral addends; Prato reaction; NON-IPR FULLERENE; ENDOHEDRAL METALLOFULLERENES; RADICAL-CATION; METAL ATOMS; CLUSTER; EPR; SC3N-AT-C-80; SC-3-AT-C-82; DERIVATIVES; DYNAMICS;
D O I：
10.1002/anie.200906325
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The paramagnetic properties of the endohedral fullerene Sc 3C2@C80 are adjustable by exohedral modification by the Prato reaction (see picture). Analysis of spin densities and endocluster dynamics reveal unique paramagnetic properties of the Sc 3C2@C80 fulleropyrrolidine and provide general Insight Into the addenddependent paramagnetic behavior of endohedral fullerenes. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：1786 / 1789
页数：4
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