Removal of NOx and SO2 by CuO/γ-Al2O3 sorbent/catalyst in a fluidized-bed reactor

被引:60
|
作者
Jeong, SM
Kim, SD [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem Engn, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Energy & Environm Res Ctr, Taejon 305701, South Korea
关键词
D O I
10.1021/ie990482r
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Selective reduction of NO and the simultaneous removal SO2/NO by CuO/gamma-Al2O3\ sorbent/catalyst were carried out in a fluidized-bed reactor. The optimum temperature ranges for NO reduction over the fresh and sulfated CuO/gamma-Al2O3 catalyst are found to be 250-300 and 300-450 degrees C, respectively. The NO removal efficiency with the sulfated catalyst is somewhat higher than that with the fresh catalyst. The amount of optimum Cu/S is found to be 1.5 in the simultaneous removal of SO2/NO. The optimum temperature range for the simultaneous removal of SO2/NO by CuO/gamma-Al2O3 sorbent/catalyst in the reactor is 350-400 degrees C based on the SO2 and NO removal efficiencies (> 90%) and N2O formation (< 10% of NO in feed).
引用
收藏
页码:1911 / 1916
页数:6
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