Synthesis and crystal structure of [Co(pyr)2(sal)2]•H2O

被引：0

作者：

Zhong, F ^{[1
]}

Zhang, SH

Jiang, YM

Zhong, XX

机构：

[1] Jinggangshan Normal Coll, Dept Chem, Jian 343009, Peoples R China

[2] Guilin Inst Technol, Dept Chem & Mat Engn, Guilin 541004, Peoples R China

[3] Guangxi Normal Univ, Dept Chem, Guilin 541004, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2003年 / 22卷 / 03期

关键词：

cobalt complex; pyridine; salicylaldehyde; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complex [Co(pyr)(2)(sal)(2)].H2O (pyr = pyridine, sal = salicylaldehyde) has been synthesized and its crystal structure was determined to be monoclinic system with space group C2/c by single-crystal X-ray diffraction. a = 14.654(3), b = 12.247(3), c = 14.060(3) Angstrom, beta = H 6.804(4)degrees, V = 2252.1(8) Angstrom(3), Z = 4, D-c = 1.408 g/cm(3) and mu = 0.800 mm(-1). In the crystal the Co(II) ion is six-coordinated to form an octahedral polyhedron.

引用

页码：318 / 320

页数：3